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Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c7qo00588a
Abstract: Herein we present the first example of transition metal-mediated stereodefined β-OH elimination, an atom economical [Cp*RhCl2]2-catalyzed SN2′-type coupling between easily available arenes and non-terminal tertiary 2-alkynylic alcohols at rt affording fully substituted allenes with H2O…
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Keywords:
asymmetric sn2;
sn2 type;
propargylic alcohols;
type functionalization ... See more keywords
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Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc04249g
Abstract: 3-Spiropiperidino indolenines have been synthesized via novel Lewis acid-catalyzed SN2-type ring opening of activated aziridines with 1H-indoles followed by Pd-catalyzed dearomative spirocyclization with propargyl carbonates in up to 88% yields. The step and pot-economic transformation…
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Keywords:
ring opening;
spiropiperidino indolenines;
sn2 type;
activated aziridines ... See more keywords