Reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, Br) with Acids: Syntheses and molecular structures of [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– And [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– Platinum carbonyl clusters decorated by Sn(II)-Fragments
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DOI: 10.1016/j.ica.2020.119432
Abstract: Abstract The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means… read more here.
Keywords: br2sn snbr2; sncl2; snbr2 br2sn; reactions pt6 ... See more keywords
Optical and electrical properties of SnBr2-doped polyvinyl alcohol (PVA) polymeric solid electrolyte for electronic and optoelectronic applications
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DOI: 10.1016/j.ijleo.2020.166129
Abstract: Abstract A polymer electrolyte of PVA (Polyvinyl alcohol) doped with Tin (II) Bromide (SnBr2) at different weight ratios was synthesized by casting technique. The structure analysis of the composites was displayed by XRD (X-ray diffraction)… read more here.
Keywords: pva polymeric; pva; polymeric solid; electrolyte ... See more keywords