Reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, Br) with Acids: Syntheses and molecular structures of [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– And [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– Platinum carbonyl clusters decorated by Sn(II)-Fragments
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119432
Abstract: Abstract The reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, 1; Br, 2) with an excess of HBF4·Et2O afforded the new [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– (3) and [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– (4) heterometallic clusters. The molecular structures of 3 and 4 were determined by means… read more here.
Keywords: br2sn snbr2; sncl2; snbr2 br2sn; reactions pt6 ... See more keywords
Microwave-assisted synthesis of 3-aminoarylquinolines from 2-nitrobenzaldehyde and indole via SnCl2-mediated reduction and facile indole ring opening
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.03.047
Abstract: Abstract A simple and efficient one-pot two-step synthesis of substituted 3-aminoarylquinolines has been achieved from 2-nitrobenzaldehyde and indoles under microwave irradiation. Firstly 2-nitrobenzaldehydes is reduced to 2-aminobenzaldehyde in situ by commonly used chemo selective reductant… read more here.
Keywords: facile; microwave assisted; assisted synthesis; sncl2 ... See more keywords