LAUSR

Cycloaddition of isoselenocyanates to sodium and magnesium metallacycles.

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1 Published in 2022 at "Dalton transactions"

DOI: 10.1039/d1dt04366h

Abstract: Heterocumulenes SeCNR (R = C6H4OMe-2, C6H4Me-2) undergo facile cycloaddition to [(H-dpp-bian)Na(Et2O)2] (1) (H-dpp-bian = N-protonated 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) resulting in cycloadducts [(H-dpp-bian)Na(SeCNR)(DME)] (2, 3), which are the first cycloadducts derived from a sodium metallacycle reported so far.… read more here.

Keywords: sodium magnesium; dpp bian; cycloaddition isoselenocyanates; magnesium metallacycles ... See more keywords