NaI-Catalyzed Oxidative Amination of Aromatic Sodium Sulfinates: Synergetic Effect of Ethylene Dibromide and Air as Oxidants
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201801386
Abstract: A novel NaI-catalyzed oxidative amination of sodium sulfinates, employing both ethylene dibromide (EDB) and air as the oxidants, is described. EDB was first demonstrated to be a promising mild organic oxidant that in air, converted… read more here.
Keywords: nai catalyzed; oxidative amination; sodium; air ... See more keywords
A novel synthesis of aryl methyl sulfones and β-hydroxysulfones from sodium sulfinates and di-tert-butyl peroxide in H2O medium
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.12.074
Abstract: Abstract A novel and convenient synthetic route for aryl methyl sulfones and β -hydroxysulfones was developed via the radical reaction between sodium sulfinates and di- tert -butyl peroxide (DTBP). Without any catalysts and additives, the… read more here.
Keywords: aryl methyl; sulfinates tert; methyl sulfones; sodium sulfinates ... See more keywords
Efficient sulfonylation of ketones with sodium sulfinates for the synthesis of β-keto sulfones
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.09.049
Abstract: Abstract The oxidative sulfonylation of ketones with sodium sulfinates as the sulfone source and DMSO as the oxidant is reported. A series of β-keto sulfones were obtained in good to excellent yields. The advantages of… read more here.
Keywords: sodium sulfinates; sulfonylation ketones; ketones sodium; keto sulfones ... See more keywords
Direct radical sulfonylation at α-C(sp3)-H of THF with sodium sulfinates in aqueous medium
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.02.021
Abstract: Abstract A direct transition-metal-free, convenient and highly regioselective synthesis of 2-alkyl/aryl sulfonyl tetrahydrofurans (THFs) has been achieved from THF and sodium sulfinates using K2S2O8 as a mild oxidant. This one-pot simple protocol involves an efficient… read more here.
Keywords: sodium sulfinates; aqueous medium; direct radical; thf sodium ... See more keywords
Electrosynthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates mediated by NH4I
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2021.153436
Abstract: Abstract A wide range of N-unsubstituted enaminosulfones were obtained via electrochemical sulfonylation of vinyl azides with sulfonyl radicals generated from sodium sulfinates. The discovery of N-unsubstituted enaminosulfones synthesis is based on a unique ability of… read more here.
Keywords: azides sodium; electrosynthesis unsubstituted; enaminosulfones vinyl; unsubstituted enaminosulfones ... See more keywords
Photocatalytic Defluorinative Three-Component Reaction of α-Trifluoromethyl Alkenes, Alkenes, and Sodium Sulfinates: Synthesis of Monofluorocyclopentenes.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02202
Abstract: A photocatalytic three-component reaction of α-trifluoromethyl alkenes, electron-rich alkenes, and sodium sulfinates for the synthesis of gem-difluoroalkenes in a radical/polar crossover manner was developed. Due to the strong electron-withdrawing nature of the sulfonyl group, the… read more here.
Keywords: trifluoromethyl alkenes; sodium sulfinates; component reaction; three component ... See more keywords
Copper(II)-Catalyzed Alkene Aminosulfonylation with Sodium Sulfinates For the Synthesis of Sulfonylated Pyrrolidones.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00907
Abstract: A copper-catalyzed direct aminosulfonylation of unactivated alkenes with sodium sulfinates for the efficient synthesis of sulfonylated pyrrolidones is described. This reaction features good functional group tolerance and wide substrate scope, providing an efficient and straightforward… read more here.
Keywords: sulfonylated pyrrolidones; aminosulfonylation; sodium sulfinates; synthesis sulfonylated ... See more keywords
Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
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DOI: 10.1021/acsomega.9b02442
Abstract: An eco-friendly method for the synthesis of β-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature… read more here.
Keywords: sulfinates sulfonyl; sodium; sulfonyl sources; sodium sulfinates ... See more keywords
Electro-oxidation induced O-S cross-coupling of quinoxalinones with sodium sulfinates for synthesizing 2-sulfonyloxylated quinoxalines.
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DOI: 10.1039/d2cc04524a
Abstract: The functionalization of quinoxalinones is synthetically and biologically appealing, however, C2 functionalized quinoxalinones is not reported via environmentally friendly approach. Herein, we disclosed C2-O sulfonylation of quinoxalinones via our developed electrochemical oxidative O-S coupling strategy… read more here.
Keywords: sulfonyloxylated quinoxalines; sodium sulfinates; synthesizing sulfonyloxylated; electro oxidation ... See more keywords
Heterogeneous Chitosan@copper Catalyzed Selective C(sp3)–H Sulfonylation of Ketone Hydrazones with Sodium Sulfinates: Direct Access to β-Ketosulfones
Sign Up to like & getrecommendations! Published in 2023 at "Catalysts"
DOI: 10.3390/catal13040726
Abstract: The exploration of inexpensive and stable heterogeneous catalysts for C–S coupling reactions remains a challenging issue. Herein, we successfully prepared a new biomass-derived copper catalyst and applied it to the selective C(sp3)–H-directed sulfonylation of ketone… read more here.
Keywords: copper; catalyst; sodium sulfinates; selective sp3 ... See more keywords
Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates
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DOI: 10.3390/molecules24071407
Abstract: A simple copper-catalyzed redox coupling of sodium sulfinates and nitroarenes is described. In this process, abundant and stable nitroarenes serve as both the nitrogen sources and oxidants, and sodium sulfinates act as both reactants and… read more here.
Keywords: coupling nitroarenes; redox coupling; sodium sulfinates; catalyzed redox ... See more keywords