Cationic Palladium(II) Complexes for Catalytic Wacker-Type Oxidation of Styrenes to Ketones using O2 as the Sole Oxidant
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700931
Abstract: A series of new palladium(II) complexes were prepared and studied for their ability to catalyze the Wacker-type oxidation of styrenes to their corresponding acetophenones using oxygen as the sole oxidant. Catalysts are active at room… read more here.
Keywords: sole oxidant; palladium complexes; wacker type; oxidation styrenes ... See more keywords
Cascade C-H Annulation of Aldoximes with Alkynes Using O2 as the Sole Oxidant: One-Pot Access to Multisubstituted Protoberberine Skeletons.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.6b03772
Abstract: A cascade double C-H annulation of aldoximes with alkynes to produce benz[a]acridizinium salts is developed by using a simple catalytic system of [Cp*Rh(OAc)2]2 in the presence of Zn(OTf)2 with oxygen as the sole oxidant. In… read more here.
Keywords: aldoximes alkynes; sole oxidant; annulation aldoximes; pot access ... See more keywords
B2pin2-Mediated Palladium-Catalyzed Diacetoxylation of Aryl Alkenes with O2 as Oxygen Source and Sole Oxidant.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b01806
Abstract: A novel palladium-catalyzed alkene diacetoxylation with dioxygen (O2) as both the sole oxidant and oxygen source is developed, which was identified by 18O-isotope labeling studies. Control experiments suggested that bis(pinacolato)diboron (B2pin2) played a dominant intermediary… read more here.
Keywords: palladium catalyzed; oxygen source; sole oxidant; diacetoxylation ... See more keywords
Solvent-free oxidation of benzyl C-H to ketone with Co-Ni layered double hydroxide as the catalyst and O2 as the sole oxidant.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00851g
Abstract: The aerobic oxidation of ethylbenzene is an effective way to produce acetophenone, in which solvent-free conditions and oxygen as the sole oxidant are the best choice. At present, the catalytic activity and selectivity are still… read more here.
Keywords: layered double; oxidation; solvent free; sole oxidant ... See more keywords