Articles with "solution state" as a keyword



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Solution‐state doping‐assisted molecular ordering and enhanced thermoelectric properties of an amorphous polymer

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Published in 2021 at "International Journal of Energy Research"

DOI: 10.1002/er.7266

Abstract: Molecular doping of conjugated polymers is the performance‐determining step in the fabrication of organic thermoelectric devices. Although strongly oxidizing salt‐type dopants effectively produce charge carriers in polymer chains, their poor solubility in the processing solvents… read more here.

Keywords: solution state; thermoelectric properties; state doping; molecular ordering ... See more keywords
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1,6-Bis(hydrazidomethylsulfinyl)hexane: the solution state and complexation with copper(II)

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Published in 2020 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-020-2977-2

Abstract: The solution state of a new antituberculosis drug 1,6-bis(hydrazidomethylsulflnyl)hexane (L) and its complexation with copper(II) were investigated by spectrophotometry, pH-potentiometry (T = 25 °C; at variable ionic strength), and mathematical modeling. The dissociation constants of… read more here.

Keywords: hexane; solution state; bis hydrazidomethylsulfinyl; complexation ... See more keywords
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Experimental investigation of novel fast–ageing treatments for AA6082 in supersaturated solid solution state

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Published in 2019 at "Journal of Alloys and Compounds"

DOI: 10.1016/j.jallcom.2019.151934

Abstract: Abstract Developing a fast-ageing treatment can significantly reduce the current processing time (180 °C × 9 h) of high strength AA6082 automotive components. In this study, a fast ageing treatment in supersaturated solid solution state was developed, such that… read more here.

Keywords: solution state; supersaturated solid; strength; solid solution ... See more keywords
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Solution-State Hydrostatic Pressure Chemistry: Application to Molecular, Supramolecular, Polymer, and Biological Systems.

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Published in 2022 at "Accounts of chemical research"

DOI: 10.1021/acs.accounts.2c00176

Abstract: ConspectusPressure (P), as one of the most inherent state quantities, has become an academic subject of study and has attracted attention for a long time for the minute control of reaction equilibria and rates, not… read more here.

Keywords: pressure; chemistry; solution state; hydrostatic pressure ... See more keywords
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Exploration of Solid-State vs Solution-State Structure in Contact Ion Pair Systems: Synthesis, Characterization, and Solution-State Dynamics of Zinc Diphenyl Phosphate, [Zn{O2P(OPh)2}2], Donor-Base-Supported Complexes

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Published in 2023 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.2c03539

Abstract: A family of zinc phosphate complexes supported by nitrogen donor-base ligands have been synthesized, and their molecular structures were identified in both the solid (X-ray crystallography) and solution state (DOSY NMR spectroscopy). [Zn{O2P(OPh)2}2]∞ (1), formed… read more here.

Keywords: state; o2p oph; solution state;
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Contrasting Trivalent Lanthanide and Actinide Complexation by Polyoxometalates via Solution-State NMR.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c04014

Abstract: Deciphering the solution chemistry and speciation of actinides is inherently difficult due to radioactivity, rarity, and cost constraints, especially for transplutonium elements. In this context, the development of new chelating platforms for actinides and associated… read more here.

Keywords: contrasting trivalent; chemistry; trivalent lanthanide; solution state ... See more keywords
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Solution-State Long-Range MolecularOrdering in Poly(3-hexylthiophene)

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Published in 2020 at "Langmuir"

DOI: 10.1021/acs.langmuir.0c01876.s001

Abstract: A blend of poly­(3-hexylthiophene) (P3HT) and poly­(n-hexyl isocyanate-block-2-vinylpyridine) (PHIC-b-P2VP) in a common solvent shows the formation of long-range (micrometer-scale) nanowires of P3HT through hydrophobic interactions between the hexyl arms of P3HT and PHIC in a… read more here.

Keywords: state long; solution state; poly hexylthiophene; long range ... See more keywords
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Effect of Solvent on the Solution State of Conjugated Polymer P7DPF Including Single-Chain to Aggregated State Structure Formation, Dynamic Evolution, and Related Mechanisms

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Published in 2020 at "Macromolecules"

DOI: 10.1021/acs.macromol.0c00579

Abstract: The effect of solvent on the bulky polydiarylfluorene poly[4-(n-alkoxy)-9,9-diphenylfluoren-2,7-diyl]-co-[5-(n-alkoxy)-9,9-diphenylfluoren-2,7-diyl] (P7DPF) solution state including single-chain to... read more here.

Keywords: state; solution state; effect solvent; including single ... See more keywords
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Tuning the Solid- and Solution-State Fluorescence of the Iron-Chelator Deferasirox.

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c01155

Abstract: Deferasirox, an FDA-approved iron chelator, has gained increasing attention for use in anticancer and antimicrobial applications. Recent efforts by our group led to the identification of this core as an easy-to-visualize aggregation-induced emission platform, or… read more here.

Keywords: iron; emission; deferasirox; iron chelator ... See more keywords
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The elucidation of phospholipid bilayer-small molecule interactions using a combination of phospholipid nanodiscs and solution state NMR techniques.

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Published in 2020 at "Chemical communications"

DOI: 10.1039/c9cc09948d

Abstract: Quantifying phospholipid bilayer-small molecule interactions is vital to the development of new drug candidates and/or medicinal therapies. However, obtaining these data remains problematic. Herein, we detail a phospholipid nanodisc assay which enables the elucidation of… read more here.

Keywords: interactions using; solution state; phospholipid bilayer; small molecule ... See more keywords
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Solution-state NMR assignment and secondary structure propensity of the full length and minimalistic-truncated prefibrillar monomeric form of biofilm forming functional amyloid FapC from Pseudomonas aeruginosa

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Published in 2023 at "Biomolecular NMR Assignments"

DOI: 10.1101/2023.01.22.525107

Abstract: Functional bacterial amyloids provide structural scaffolding to bacterial biofilms. In contrast to the pathological amyloids, they have a role in vivo and are tightly regulated. Their presence is essential to the integrity of the bacterial… read more here.

Keywords: nmr assignment; state nmr; fapc; biofilm forming ... See more keywords