Lignin Depolymerisation and Lignocellulose Fractionation by Solvated Electrons in Liquid Ammonia.
Sign Up to like & getrecommendations! Published in 2017 at "ChemSusChem"
DOI: 10.1002/cssc.201601608
Abstract: We explored the depolymerisation of several lignins in liquid ammonia at relatively high temperatures and pressures (120 °C and 88 bar). Five different lignins were tested: Indulin AT kraft, Protobind 1000 soda, wheat straw organosolv, poplar organosolv… read more here.
Keywords: fractionation; lignin; solvated electrons; liquid ammonia ... See more keywords
Hydrogen plasma treated nanodiamonds lead to an overproduction of hydroxyl radicals and solvated electrons in solution under ionizing radiation
Sign Up to like & getrecommendations! Published in 2020 at "Carbon"
DOI: 10.1016/j.carbon.2020.02.063
Abstract: Abstract In numerous fields of application (environmental remediation, catalysis, nanomedicine), production of hydroxyl radicals and solvated electrons by nanomaterials is a cornerstone. Through a very sensitive, nanoparticle-compatible, coumarin-based protocol, we quantified hydroxyl radicals in solution… read more here.
Keywords: radicals solvated; hydrogen plasma; solution; solvated electrons ... See more keywords
Chemistry of Solvated Electrons in Molten Alkali Chloride Salts
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b05716
Abstract: We use ab initio molecular dynamics to study the electronic structure and the chemistry of the solvated electrons created when alkali atoms are dissolved in alkali chloride molten salt. We find that solvated electrons pair… read more here.
Keywords: electrons molten; alkali chloride; chemistry; chemistry solvated ... See more keywords
Solvated Electrons for Photochemistry Syntheses Using Conjugated Carbon Nitride Polymers
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DOI: 10.1021/acscatal.9b00314
Abstract: Solvated electrons have attracted increasing research interest due to their strong reducing ability. However, the generation and utilization of solvated electrons in photocatalytic systems are rare... read more here.
Keywords: syntheses using; photochemistry syntheses; conjugated carbon; electrons photochemistry ... See more keywords
Plasmon-Generated Solvated Electrons for Chemical Transformations.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07768
Abstract: Methods for generating solvated electrons─free electrons in solution─have focused primarily on alkali metal ionization or high-energy electrons or photons. Here we report the generation of solvated electrons by exciting the plasmon resonance of Al nanocrystals… read more here.
Keywords: reaction; chemical transformations; plasmon generated; solvated electrons ... See more keywords
Creation and Reaction of Solvated Electrons at and near the Surface of Water.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c03370
Abstract: Solvated electrons (es-) are among nature's most powerful reactants, with over 2600 reactions investigated in bulk water. These electrons can also be created at and near the surface of water by exposing an aqueous microjet… read more here.
Keywords: near surface; reaction; water; solvated electrons ... See more keywords
Nitrogen reduction utilizing solvated electrons produced by thermal excitation of trapped electrons in reduced titanium oxide
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00560e
Abstract: Heterogeneous catalytic dinitrogen reduction to produce ammonia at ambient pressure and temperature is a challenging task when attempting to mimic the natural dinitrogen fixation process because the N2 molecule hardly binds with solid catalytic materials… read more here.
Keywords: reduction; energy; solvated electrons; electrons produced ... See more keywords