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Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00151
Abstract: ConspectusA decisive factor for obtaining high yields and selectivities in organic synthesis is the choice of the proper solvent. Solvent selection is often guided by the intuitive understanding of transition state-solvent interactions. However, quantum-mechanical tunneling…
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Keywords:
solvation effects;
quantum tunneling;
hydrogen;
solvent ... See more keywords
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Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00295
Abstract: 1-Hexene polymerization using four zirconium-based amine bis(phenolate) catalysts, Zr[2-R-4-tBu-ONNO]Bn2 (where R = methyl (1), ethyl (2), isopropyl (3), and tert-butyl (4)), was examined to establish the effect of ligand sterics on kinetics and stereocontrol of…
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Keywords:
polymerization;
polymerization kinetics;
dormancy;
steric solvation ... See more keywords