Solvent-dependent inversion of circular dichroism signal in naproxen: An unusual effect!
Sign Up to like & getrecommendations! Published in 2018 at "Chirality"
DOI: 10.1002/chir.22988
Abstract: The electronic circular dichroism (ECD) spectra of naproxen enantiomers were studied as a function of solvents using experimental (circular dichroism) and theoretical (time-dependent density functional theory) approaches. The (R)- and (S)-naproxen enantiomers presented an unusual… read more here.
Keywords: dichroism; solvent dependent; inversion circular; circular dichroism ... See more keywords
Solvent-dependent helix inversion in optically active poly(diphenylacetylene)s and their chiral recognition abilities as chiral stationary phases for high-performance liquid chromatography.
Sign Up to like & getrecommendations! Published in 2022 at "Chirality"
DOI: 10.1002/chir.23416
Abstract: We report the first example of solvent-dependent helix inversion in poly(diphenylacetylene) (PDPA) derivatives. Asymmetrically substituted PDPAs bearing optically active substituents linked through amide bonds formed preferred-handed helical conformations because of the optically active substituents in… read more here.
Keywords: dependent helix; solvent dependent; optically active; helix inversion ... See more keywords
Solvent‐Dependent Reactivity and Photochemistry of Dinuclear and Mononuclear Platinum(IV) Azido Triazaolato Complexes
Sign Up to like & getrecommendations! Published in 2021 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202100041
Abstract: Abstract Reaction between the platinum(IV) azido complex trans,trans,trans‐[Pt(py)2(N3)2(OH)2] (1) and 1,4‐diphenyl‐2‐butyne‐1,4‐dione 2 in MeCN produces the intermediate peroxide‐bridged dimeric platinum(IV) azido triazolato species (5), which has been characterised by X‐ray crystallography. However, if the reaction… read more here.
Keywords: platinum azido; dependent reactivity; platinum; trans trans ... See more keywords
Solvent-dependent transformation of aflatoxin B1 in soil
Sign Up to like & getrecommendations! Published in 2017 at "Mycotoxin Research"
DOI: 10.1007/s12550-017-0278-x
Abstract: To date, all studies of aflatoxin B1 (AFB1) transformation in soil or in purified mineral systems have identified aflatoxins B2 (AFB2) and G2 (AFG2) as the primary transformation products. However, identification in these studies was… read more here.
Keywords: afb1 soil; solvent dependent; transformation; soil ... See more keywords
Solvent-dependent and visible light-activated NIR photochromic dithienylethene modified by difluoroboron β-diketonates as fluorescent turn-on pH sensor
Sign Up to like & getrecommendations! Published in 2019 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2018.10.049
Abstract: Abstract The development of near-infrared (NIR) photochromic materials, particularly activated by visible light, are of increasing interest for their potential application in photoresponsive optoelectronics and functional bio-materials. Here, a novel D-DTE-A type dithienylethene NDB, which… read more here.
Keywords: visible light; dithienylethene; solvent dependent; modified difluoroboron ... See more keywords
Solvent dependent relaxation dynamics in lithium ion battery electrolytes: Coupling to medium friction
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2019.111225
Abstract: Abstract Solution heterogeneity and dynamics of the industrially relevant electrolyte system, [9.795{xEC + (1 − x)PC} + 0.869LiClO4] with x representing mole fraction, were explored at different loadings of ethylene carbonate (EC) via temperature dependent measurements of time-resolved spectral response and… read more here.
Keywords: time resolved; dynamics lithium; solvent dependent; electrolyte systems ... See more keywords
Conformation of repaglinide: A solvent dependent structure
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.04.097
Abstract: Abstract Experimental and theoretical conformational study of repaglinide in chloroform and dimethyl sulfoxide was investigated. By applying potential energy scanning (PES) at B3LYP/6-311++g** and B3LYP-D3/6-311++g** level of theory on rotatable single bonds, four stable conformers… read more here.
Keywords: structure conformation; repaglinide solvent; solvent dependent; structure ... See more keywords
Solvent-Dependent Sensitization of Ytterbium and Neodymium via an Intramolecular Excimer.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02709
Abstract: We report the synthesis of a di(1-pyrenyl)phosphoryl acetophenone ligand containing two pyrenyl moieties linked by a single phosphorus atom. The ligand exhibits solvent-dependent emission: in nonpolar solvents, typical monomeric pyrene emission is observed, whereas in… read more here.
Keywords: ytterbium; solvent dependent; intramolecular excimer; neodymium ... See more keywords
Solvent-dependent selective cation exchange in anionic frameworks based on cobalt(ii) and triphenylamine linkers: reactor-dependent synthesis and sorption properties.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01405h
Abstract: Two cobalt(ii) coordination polymers with anionic networks of formulae {(Me2NH2)2[CoCl(ntb)]}n (JUMP-2) and {(Me2NH2)2[Co5(ntb)4(H2O)3(Me2NH)]}n (previously reported as MIL-144 by Livage et al., Microporous Mesoporous Mater., 2012, 157, 37) have been obtained via a solvothermal reaction of… read more here.
Keywords: cation; mil 144; solvent dependent; exchange ... See more keywords
Solvent-dependent, rhodium catalysed rearrangement reactions of sulfur ylides.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03809d
Abstract: Benzyl thioethers undergo rhodium(ii) catalyzed sigmatropic rearrangement reactions with aryldiazoacetates. Depending on the solvent and the electronic properties of the sulfide, the intermediate ylide undergoes either [1,2]- or [2,3]-sigmatropic rearrangement reactions in high yields. read more here.
Keywords: rearrangement reactions; rhodium; solvent dependent; rhodium catalysed ... See more keywords
Solvent-controlled and solvent-dependent strategies for the synthesis of multicolor carbon dots for pH sensing and cell imaging
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c9tc02422k
Abstract: Solvent-controlled, pH-dependent and solvent-dependent strategies are proposed to obtain multicolor carbon dots using the same precursor. read more here.
Keywords: dependent strategies; carbon dots; multicolor carbon; solvent dependent ... See more keywords