Solvent-induced Gel Formation Hypothesis for Natural Product Gelators with Polycyclic Structures.
Sign Up to like & getrecommendations! Published in 2018 at "ChemPlusChem"
DOI: 10.1002/cplu.201800334
Abstract: Natural products have long been used as pharmaceutical actives for the treatment of diseases. More recently, natural products with the ability to self-assemble to form soft material-gels, i.e. natural product gelators (NPGs), were discovered. This… read more here.
Keywords: gel formation; product gelators; formation; induced gel ... See more keywords
Visualization of Solvent-Induced Structure Evolution in Cyclodextrin Polyrotaxane Gels.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200082
Abstract: Cyclodextrin (CD)-based polyrotaxanes (PR) are widely used to construct high-mechanical-performance materials because of the high degree of conformational freedom. However, strong hydrogen bonds between CDs greatly limit the application of CD-PR in the preparation of… read more here.
Keywords: visualization solvent; solvent induced; structure evolution; induced structure ... See more keywords
Anion- and solvent induced modulation of photophysical properties of a luminescent bimetallic Ru(II) complex: Experimental and TD-DFT study
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119337
Abstract: Abstract Anion- and solvent induced modulation of phtophysical behavior of a binuclear Ru(II) complex of the type [(bpy)2Ru(H2L)Ru(bpy)2]4+, where H2L = 2,5-bis[1,10]phenanthroline[4,5-f]-imidazol-2-yl)thiophene} and bpy = 2,2′-bipyridine was thoroughly investigated in this work. The complex shows strong room temperature emission… read more here.
Keywords: dft; anion solvent; solvent; induced modulation ... See more keywords
Effect of bimodal pores on sintering and residual stresses of YSZ membranes prepared by non-solvent induced phase separation method
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the European Ceramic Society"
DOI: 10.1016/j.jeurceramsoc.2018.12.037
Abstract: Abstract Densification mismatch and residual stresses of tri-layered yttria-stabilized zirconia (YSZ) membranes prepared by a non-solvent induced phase separation (NIPS) method were investigated. The tri-layered membrane consisted of sponge-like structures and finger-like voids in macroscale.… read more here.
Keywords: membranes prepared; ysz membranes; non solvent; solvent induced ... See more keywords
Solvent induced supramolecular polymorphism in Cu(II) coordination complex built from 1,2,4-triazolo[1,5-a]pyrimidine: Crystal structures and anti-oxidant activity.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111092
Abstract: Two Cu(II) coordination complexes, C1 and C2 of the formula [Cu(4)2(H2O)2], have been prepared by reaction between CuCl2·2H2O and 7-ethoxycarbonylmethyl-5-methyl-1,2,4[1,5-a]pyrimidine (L) in a 1:2 M:L molar ratio. The L molecule decomposes during the reaction process… read more here.
Keywords: triazolo pyrimidine; coordination; pyrimidine; solvent induced ... See more keywords
Solvent induced supramolecular anisotropy in molecular gels
Sign Up to like & getrecommendations! Published in 2017 at "Materials Chemistry and Physics"
DOI: 10.1016/j.matchemphys.2017.03.044
Abstract: Abstract Herein is the first report of solvent induced anisotropy in 12-hydroxystearic acid self-assembled fibrillar networks. Increasing the chain length of polar solvent, such as nitriles and ketones, tailored the anisotropy of the fibrillar aggregates.… read more here.
Keywords: chain; molecular gels; supramolecular anisotropy; solvent induced ... See more keywords
Magnolia-like terbium-based metal-organic frameworks hierarchical architectures: Solvent-induced synthesis, microstructure and enhanced luminescent properties
Sign Up to like & getrecommendations! Published in 2018 at "Optical Materials"
DOI: 10.1016/j.optmat.2018.05.014
Abstract: Abstract An efficient and facile route for the solvent-induced synthesis of magnolia-like terbium-based metal-organic frameworks (Tb-MOFs) architectures has been developed at room temperature. The effect of ethanol volume ratio (R) on the microstructure and morphological… read more here.
Keywords: terbium based; like terbium; induced synthesis; solvent induced ... See more keywords
Polyhydroxyalkanoate (PHA) based microfiltration membranes: Tailoring the structure by the non-solvent induced phase separation (NIPS) process
Sign Up to like & getrecommendations! Published in 2020 at "Polymer"
DOI: 10.1016/j.polymer.2020.122813
Abstract: Abstract Within the purpose of developing more sustainable membrane systems, it is herein proposed to implement a biobased and biodegradable material, the poly(hydroxybutyrate-co-hydroxyvalerate) (PHBHV), to replace conventional polymers in a commonly used membrane fabrication process.… read more here.
Keywords: phase separation; induced phase; non solvent; process ... See more keywords
Solvent-induced protein precipitation for drug target discovery on proteomic scale.
Sign Up to like & getrecommendations! Published in 2019 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.9b04531
Abstract: High-throughput drug discovery is highly depended on the targets available to accelerate the process of candidates screening. Traditional chemical proteomics approaches for the screening of drug targets usually require the immobilization/modification of the drug molecules… read more here.
Keywords: drug; discovery; drug target; solvent induced ... See more keywords
Solvent-Induced Structural Transformation and Luminescence Response in a Dumbbell-Shaped Crystalline Molecular Rotor.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03504
Abstract: Crystalline molecular rotors constitute a new class of stimuli-responsive molecular materials owing to inherent molecular dynamics. However, beyond the molecular level, the role of molecular packings on the bulk structures and related properties has yet… read more here.
Keywords: molecular rotor; crystalline molecular; transformation; rotor ... See more keywords
Solvent-Induced Spin-State Change in Copper Corroles.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02678
Abstract: The electronic structure of copper corroles has been a topic of debate and revision since the advent of corrole chemistry. The ground state of these compounds is best described as an antiferromagnetically coupled Cu(II) corrole… read more here.
Keywords: solvent induced; chemistry; copper corroles; spin state ... See more keywords