Organometallic flow chemistry: solvento complexes.
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DOI: 10.1039/d2dt02583c
Abstract: Photolysis under optimised flow conditions of metal carbonyls [{Ln}M(CO)x] [{Ln}M(CO)x = Cr(CO)6, Mo(CO)6, W(CO)6, Mn(CO)3(η-C5H4Me), Re(CO)3(η-C5H5)] in tetrahydrofuran (THF) conveniently affords the synthetically versatile and labile solvento complexes [{Ln}M(CO)x-1(THF)], thereby obviating many of the caveats… read more here.
Keywords: organometallic flow; chemistry; solvento complexes; flow chemistry ... See more keywords