Model Compounds for Intermediates and Transition States in Sonogashira and Negishi Coupling: d8-d10 Bonds in Large Heterobimetallic Complexes Are Weaker than Computational Chemistry Predicts.
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DOI: 10.1021/jacs.2c01641
Abstract: We report an experimental study, with accompanying DFT calculations, on a series of heterobimetallic complexes with Pd(II) and Cu(I), Ag(I), or Au(I). The isolable pincer complexes are models for the intermediates and transition state for… read more here.
Keywords: heterobimetallic complexes; chemistry; sonogashira negishi; negishi coupling ... See more keywords