Synthesis, crystal structure, and characterization of cyclohexylammonium tetraisothiocyanatocobaltate(II): A single-source precursor for cobalt sulfide and oxide nanostructures
Sign Up to like & getrecommendations! Published in 2019 at "Heliyon"
DOI: 10.1016/j.heliyon.2019.e01139
Abstract: We successfully synthesized 3D supramolecular structure of cyclohexylammonium tetraisothiocyanatocobaltate(II) complex, (C6H11NH3)2[Co(NCS)4], in almost a quantitative yield by using metathesis and ligand addition reactions. The new complex was characterized by various techniques such as FTIR, UV-Visible,… read more here.
Keywords: single source; cyclohexylammonium tetraisothiocyanatocobaltate; source precursor; cobalt sulfide ... See more keywords
Encapsulating ruthenium in silica using a single source precursor: Differing outcomes for a cycloaddition reaction
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119833
Abstract: Abstract The complex [Ru2(CO)4(µ-O2CCH2OSi(OEt)3)2(PPh3)2] was used as a single-source precursor to prepare silica-encapsulated ruthenium via hydrolysis followed by calcination. While the silica-encapsulated ruthenium catalyst and the molecular precursor both catalysed the [2 + 1] cycloaddition reaction between… read more here.
Keywords: single source; silica; precursor; source precursor ... See more keywords
A heterobimetallic single-source precursor enabled layered oxide cathode for sodium-ion batteries.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc04205e
Abstract: A single-source precursor NaCo(acac)3 (acac = acetylacetone) for layered oxide cathodes of sodium-ion batteries (SIBs) is reported here. It features a 1D chain structure, and is prepared in nearly quantitative yield employing commercially available reagents.… read more here.
Keywords: sodium ion; single source; oxide cathode; layered oxide ... See more keywords
[Ge(TenBu)4] - a single source precursor for the chemical vapour deposition of germanium telluride thin films.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03263g
Abstract: Reaction of activated germanium with nBu2Te2 in THF solution was shown to be more effective for the preparation of the germanium(iv) tellurolate compound, [Ge(TenBu)4], than reaction of GeCl4 with LiTenBu in a 1 : 4 molar ratio… read more here.
Keywords: single source; thin films; germanium; deposition ... See more keywords
Facile synthesis of a hexanuclear zinc-acetato-trimethylsilylphosphinidene cluster: a single-source precursor to Zn3P2 nanoparticles.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc04879k
Abstract: The selective synthesis of the zinc-acetato-phosphinidene cluster [Zn6(μ3-PSiMe3)4(OAc)4(NC5H5)5] 1 is presented. The cluster serves as a stable, single-source precursor to yield soluble zinc phosphide nanoparticles via P-Si bond activation and AcOSiMe3 elimination when heated in… read more here.
Keywords: single source; zinc; zinc acetato; source precursor ... See more keywords
Transition metal chalcogenide bifunctional catalysts for chemical recycling by plastic hydrocracking: a single-source precursor approach
Sign Up to like & getrecommendations! Published in 2022 at "Royal Society Open Science"
DOI: 10.1098/rsos.211353
Abstract: Sulfided nickel, an established hydrocracking and hydrotreating catalyst for hydrocarbon refining, was synthesized on porous aluminosilicate supports for the hydrocracking of mixed polyolefin waste. Zeolite beta, zeolite 13X, MCM41 and an amorphous silica-alumina catalyst support… read more here.
Keywords: catalyst; source precursor; beta; single source ... See more keywords