Decomposition of single-source precursors under high-temperature high-pressure to access osmium–platinum refractory alloys
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Alloys and Compounds"
DOI: 10.1016/j.jallcom.2019.152121
Abstract: Abstract Thermal decomposition of (NH4)2[OsxPt1-xCl6] as single-source precursors for Os–Pt binary alloys has been investigated under ambient and high pressure up to 40 GPa. Thermal decomposition of mixed-metal (NH4)2[OsxPt1-xCl6] precursors in hydrogen atmosphere (reductive environment) under… read more here.
Keywords: single source; source precursors; high pressure; decomposition ... See more keywords
Single-Source Precursors for Lanthanide Diselenide Nanosheets
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.9b03067
Abstract: A series of complexes of the type [Ln(Se2P(phenyl)2)3(CH3CN)x] (x = 1 or 2) have been synthesized and structurally characterized for Ln = La–Lu (excluding Pm). The complexes are straightforward to prepare and crystallize and are… read more here.
Keywords: single source; source precursors; microscopy; diselenide nanosheets ... See more keywords
Alkali Metal Di-tert-butyl Phosphates: Single-Source Precursors for Homo- and Heterometallic Inorganic Phosphate Materials.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00094
Abstract: The reaction of alkali metal acetates, M(OAc)·nH2O (M = Li, Na, K), with thermally and hydrolytically unstable di-tert-butylphosphate ((tBuO)2PO2H, dtbp-H) in a 1:1 molar ratio in MeOH at room temperature leads to clean formation of… read more here.
Keywords: phosphate; tert butyl; single source; source precursors ... See more keywords
Synthesis of Heterometallic Zirconium Alkoxide Single-Source Precursors for Bimetallic Oxide Deposition
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02852
Abstract: Single-source precursors are ubiquitous in a number of areas of chemistry and material science due to their ease of use and wide range of potential applications. The development of new single-source precursors is essential in… read more here.
Keywords: zirconium; chemistry; single source; source precursors ... See more keywords
Single-Source Precursors for the Controlled Aqueous Synthesis of Bismuth Oxyhalides.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c01114
Abstract: Bismuth oxyhalides are a promising class of photocatalysts for harvesting solar energy. These materials are often synthesized in aqueous media with poor synthetic control resulting from the extremely fast nucleation and growth rates of the… read more here.
Keywords: single source; synthesis; source precursors; bismuth oxyhalides ... See more keywords
Aerosol-Assisted Chemical Vapor Deposition of ZnS from Thioureide Single Source Precursors.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03363
Abstract: A family of 12 zinc(II) thoureide complexes, of the general form [{L}ZnMe], [{L}Zn{N(SiMe3)2}], and [{L}2Zn], have been synthesized by direct reaction of the thiourea pro-ligands iPrN(H)CS(NMe2) H[L1], CyN(H)CS(NMe2) H[L3], tBuN(H)CS(NMe2) H[L2], and MesN(H)CS(NMe2) H[L4] with… read more here.
Keywords: single source; aerosol assisted; zns; source precursors ... See more keywords
Direct Writing of Cobalt Silicide Nanostructures Using Single-Source Precursors.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c14117
Abstract: Two new precursors for focused electron beam-induced deposition (FEBID) of cobalt silicides have been synthesized and evaluated. The H3SiCo(CO)4 and H2Si(Co(CO)4)2 single-source precursors retain the initial metal ratios and show low sensitivity to changes in… read more here.
Keywords: single source; cobalt; direct writing; metal ... See more keywords
Heterobimetallic Single-Source Precursors: A Springboard to the Synthesis of Binary Intermetallics
Sign Up to like & getrecommendations! Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.9b00088
Abstract: Intermetallics are atomically ordered crystalline compounds containing two or more main group and transition metals. In addition to their rich crystal chemistry, intermetallics display unique properties of interest for a variety of applications, including superconductivity,… read more here.
Keywords: single source; source precursors; synthesis binary; synthesis ... See more keywords
Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield ceramic phosphates
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce01066d
Abstract: Building up on an available synthetic methodology, phosphate monoesters ROPO3H2 have been synthesized in good yields. The synthetic procedure employed features acetic anhydride mediated activation of phosphoric acid in the presence of alcohols, leading to… read more here.
Keywords: single source; chemistry; ceramic phosphates; source precursors ... See more keywords
Complex salts of Pd(II) and Pt(II) with Co(II) and Ni(II) aqua-cations as single-source precursors for bimetallic nanoalloys and mixed oxides
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00956b
Abstract: A series of highly soluble double complex salts [M′(H2O)6][M′′(NO2)4]·2H2O (M′ = Ni, Co; M′′ = Pd, Pt) have been synthesized, studied and used as single-source precursors for bimetallic nanoalloys and metal–oxide composites. According to the… read more here.
Keywords: single source; bimetallic nanoalloys; precursors bimetallic; complex salts ... See more keywords