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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02751
Abstract: Sulfonamide-containing (hetero)arenes are widely present in bioactive molecules. Here, we report the sulfonamidyl (hetero)arenes synthesis by the C(sp2)-H amidation from bench-stable amidyl-iminophenylacetic acids. The hypervalent iodine reagents covalently activated iminophenylacetic acids for the facile sulfonamidyl…
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Keywords:
hypervalent iodine;
iodine reagents;
iminophenylacetic acids;
hetero arenes ... See more keywords
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Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc04904a
Abstract: An efficient and convenient ligand-free, rhodium-catalyzed ortho-C(sp2)-H amidation of benzaldehydes with dioxazolones using H2O as the key promoter is described. Using this protocol, a wide range of benzaldehyde substrates were selectively amidated in good to…
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Keywords:
ligand free;
benzaldehydes dioxazolones;
sp2 amidation;
amidation benzaldehydes ... See more keywords