Palladium-catalyzed C(sp2)–H aminoimidoylation of isocyano-containing arenes: synthesis of amino substituted N-heterocycles
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DOI: 10.1039/c7qo00368d
Abstract: An efficient access to amino substituted phenanthridine and isoquinoline derivatives, through palladium-catalyzed C(sp2)–H aminoimidoylation, has been developed. This process applies O-benzoyl hydroxylamines as oxidative amino sources to generate amino Pd(II) intermediates, followed by isocyanide insertion… read more here.
Keywords: amino; catalyzed sp2; palladium catalyzed; sp2 aminoimidoylation ... See more keywords