Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp2)-H Borylation of Benzoate Esters and Arylboronate Esters.
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DOI: 10.1016/j.chempr.2020.11.017
Abstract: Synthetic and mechanistic investigations into the C(sp2)-H borylation of various electronically diverse arenes catalyzed by bis(phosphine)pyridine (iPrPNP) cobalt complexes are reported. Borylation of various benzoate esters and arylboronate esters gave remarkably high selectivities for the… read more here.
Keywords: borylation; regioselectivity; sp2 borylation; benzoate esters ... See more keywords