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Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00330
Abstract: The FeIII(phen)3 catalysis of the benzylic C(sp3)-H azidation of indoles has been investigated. The Fe(III) complex can selectively oxidize indoles to form arene radical cations, which are transformed into benzylic C(sp3) radical intermediates. This strategy…
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Keywords:
sp3 azidation;
catalysis;
strategy;
iron catalysis ... See more keywords
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1
Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00425a
Abstract: C-H Azidation is an increasingly important tool for bioconjugation, materials chemistry, and the synthesis of nitrogen-containing natural products. While several approaches have been developed, these often require exotic and energetic reagents, expensive photocatalysts, or both.…
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Keywords:
sp3 azidation;
azidation;
decatungstate photocatalysed;
photocatalysed sp3 ... See more keywords