Double α,α CH bond insertion into sp3 CH2 moiety: synthesis of a Fe carbene bis-hydride dinitrogen complex.
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DOI: 10.1039/d1dt00610j
Abstract: Reduction of high spin paramagnetic complex [(κ2-P, P'-PCH2PCy)FeCl2] 2 by two electrons under N2 resulted in the formation of two isomeric low spin diamagnetic complexes 3trans and 3cis [Fe(κ3-P,C,P'-PCPCy)(H)2(N2)]. Cristallization allowed isolation of complex 3d… read more here.
Keywords: sp3 ch2; ch2 moiety; bond insertion; double bond ... See more keywords