Radical C(sp3)-H Heck-type Reaction of N-Alkoxybenzimidoyl Chlorides with Styrenes to Construct Alkenols.
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DOI: 10.1021/acs.orglett.2c00593
Abstract: We report the first radical C(sp3)-H Heck-type reaction of aliphatic alcohols for selective δ- and ε-alkenol synthesis by photoredox catalysis. N-Alkoxybenzimidoyl chlorides are developed as novel alkoxyl radical precursors with tunable redox potentials. Various alkenols… read more here.
Keywords: alkoxybenzimidoyl chlorides; heck type; sp3 heck; type reaction ... See more keywords