Ag-Catalyzed Remote Unactivated C(sp3)-H Heteroarylation of Free Alcohols in Water.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.0c03944
Abstract: Catalyzed by silver salt, the unactivated C(sp3)-H heteroarylation of free alcohol at the δ position is realized under gentle thermal conditions in water through a radical procedure. Both protonic acids and Lewis acids are found… read more here.
Keywords: unactivated sp3; water; catalyzed remote; heteroarylation free ... See more keywords
Photoredox-mediated remote C(sp3)–H heteroarylation of free alcohols† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04134b
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c8sc04134b
Abstract: We report an efficient and economical method for remote δ C(sp3)–H heteroarylation of free aliphatic alcohols using a hypervalent iodine PFBI-OH oxidant under photoredox catalysis. read more here.
Keywords: remote sp3; sp3 heteroarylation; heteroarylation free; photoredox mediated ... See more keywords