Visible Light as a Sole Requirement for Intramolecular C(sp3)-H Imination.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b00533
Abstract: A novel, simple, and practical visible-light-mediated intramolecular α-C(sp3)-H imination of tertiary aliphatic amines containing β-O-aryl oximes leading to N-heterocycles has been developed. The reaction was performed well at rt with tolerance of some functional groups.… read more here.
Keywords: sp3 imination; sole requirement; visible light; light sole ... See more keywords
An intramolecular C(sp3)-H imination using PhI-mCPBA.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc09100e
Abstract: Herein, a highly exothermic primary amine-polyvalent iodine reaction has been used successfully for selective functionalization of acidic C(sp3)-H groups for a dehydrogenative C-H imination reaction by 4H elimination. Overall, C(sp3)-H imination at 1,5 distances was… read more here.
Keywords: sp3 imination; imination; imination using; using phi ... See more keywords