Structural, spectral, electrochemical and DFT studies of two mononuclear manganese(II) and zinc(II) complexes
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DOI: 10.1016/j.poly.2016.11.032
Abstract: Abstract Two mononuclear M(II) complexes, [M(L2)2]·CH3OH (M = Mn(1) and Zn(2), HL2 = 1-(2-{[(E)-3,5-dibromo-2-hydroxybenzylidene]amino}phenyl)ethanone oxime), were synthesized via complexation of corresponding M(II) acetate with HL1 (2-(3,5-dibromo-2-hydroxyphenyl)-4-methyl-1,2-dihydroquinazoline-3-oxide, H is the deprotonatable hydrogen) originally. During the reaction, the C–N bond in… read more here.
Keywords: dft; two mononuclear; geometry; electrochemical dft ... See more keywords
Spectral, Electrochemical, and ESR Characterization of Manganese Tetraarylporphyrins Containing Four β,β'-Pyrrole Fused Butano and Benzo Groups in Nonaqueous Media.
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DOI: 10.1021/acs.inorgchem.8b03184
Abstract: Two series of β,β'-pyrrole butano- and benzo-substituted mangenese(III) tetraarylporphyrins were synthesized and characterized with regard to their spectral and electrochemical properties. The investigated compounds have the general formula butano(Ar)4PorMnCl and benzo(Ar)4PorMnCl, where Por is the… read more here.
Keywords: pyrrole; butano benzo; benzo; porphyrin ... See more keywords