Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.
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DOI: 10.1021/acs.inorgchem.7b00448
Abstract: In this report we compare the geometric and electronic structures and reactivities of [FeV(O)]- and [FeIV(O)]2- species supported by the same ancillary nonheme biuret tetraamido macrocyclic ligand (bTAML). Resonance Raman studies show that the Fe═O… read more here.
Keywords: spectroscopic reactivity; comparisons pair; reactivity comparisons; btaml ... See more keywords
Spectroscopic and reactivity differences in metal complexes derived from sulfur containing Triphos homologs.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01459g
Abstract: Herein, we report a simplified method for the synthesis of Triphos homologs H3CC(CH2X)n(CH2Y)3-n (X = SPh, Y = PPh2, n = 0-3). The multidentate compounds were tested for their potential to coordinate metals such as… read more here.
Keywords: reactivity differences; metal complexes; spectroscopic reactivity; triphos homologs ... See more keywords