Unraveling the Potential of Vinyl Ether as an Ethylene Surrogate in Heteroarene C─H Functionalization via the Spin‐Center Shift
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DOI: 10.1002/advs.202309800
Abstract: Despite the simplicity and abundance of ethylene, its practical application presents significant hurdles due to its nature as a highly flammable gas. Herein, a strategic use of easily handled vinyl ether is reported as a… read more here.
Keywords: via spin; vinyl ether; ethylene; ethylene surrogate ... See more keywords
Defluorinative Alkylation of Trifluoromethylbenzimidazoles Enabled by Spin-Center Shift: A Synergistic Photocatalysis/Thiol Catalysis Process with CO2•.
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DOI: 10.1021/acs.orglett.2c01533
Abstract: We describe a catalytic strategy for direct single C(sp3)-F bond alkylation of trifluoromethylbenzimidazoles under a photoinduced thiol catalysis process. The CO2 radical anion (CO2•-) proved to be the most efficient single-electron reductant to realize such… read more here.
Keywords: catalysis process; process co2; spin center; alkylation trifluoromethylbenzimidazoles ... See more keywords