Photoinduced transformation of glycerol in titania suspensions. (An EPR spin trapping study of radical intermediates)
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Today"
DOI: 10.1016/j.cattod.2017.12.005
Abstract: Abstract Formation of radical intermediates upon photocatalytic (UVA) glycerol transformation in aerated aqueous TiO2 (P25) suspensions was followed by EPR spin trapping technique. Character and concentration of the spin-adducts generated by the addition of the… read more here.
Keywords: radical intermediates; glycerol; transformation; spin ... See more keywords
In Situ EPR Spin Trapping and Competition Kinetics Demonstrate Temperature-Dependent Mechanisms of Synergistic Radical Production by Ultrasonically Activated Persulfate.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.1c08562
Abstract: Ultrasound coupled with activated persulfate can synergistically degrade aqueous organic contaminants. Here, in situ electron paramagnetic resonance spin trapping was used to compare radicals produced by ultrasonically activated persulfate (US-PS) and its individual technologies, ultrasound… read more here.
Keywords: temperature; ultrasonically activated; spin trapping; activated persulfate ... See more keywords
Spin-Trapping Analysis and Characterization of Thermal Degradation of Thermoplastic Poly(ether–ester) Elastomer
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b02654
Abstract: We investigated the thermal degradation of poly(butylene terephthalate)-co-poly(ethylene oxide) (PBT-co-PEO), a thermoplastic poly(ether–ester) elastomer (TPEE), through proton nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), gel permeation… read more here.
Keywords: degradation; thermal degradation; analysis; poly ... See more keywords
Para-Substituted α-Phenyl-N-tert-butyl Nitrones: Spin-Trapping, Redox and Neuroprotective Properties
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DOI: 10.1021/acsomega.0c03907
Abstract: In this work, a series of para-substituted α-phenyl-N-tert-butyl nitrones (PBN) were studied. Their radical-trapping properties were evaluated by electron paramagnetic resonance, with 4-CF3-PBN being the fastest derivative to trap the hydroxymethyl radical (•CH2OH). The redox… read more here.
Keywords: para substituted; butyl nitrones; phenyl tert; tert butyl ... See more keywords
Electron paramagnetic resonance and spin trapping to detect free radicals from allergenic hydroperoxides in contact with the skin: From the molecule to the tissue
Sign Up to like & getrecommendations! Published in 2022 at "Contact Dermatitis"
DOI: 10.1111/cod.14037
Abstract: A major research topic consists of revealing the contribution of radical‐mediated reactions in dermatological diseases related to xenobiotic‐induced stress to succeed risk‐assessment procedures protecting producers and consumers. Allergic contact dermatitis is the clinically relevant consequence… read more here.
Keywords: electron paramagnetic; paramagnetic resonance; spin trapping; tissue ... See more keywords
Molecular Structure of Poly(vinyl alcohol)-Derived Carbon-Centered Radicals Studied by Rapid-Flow and Spin-Trapping ESR Measurements: A Short-Lived Intermediate Radical in the Initial Stage of the Graft Polymerization Reaction
Sign Up to like & getrecommendations! Published in 2017 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1246/bcsj.20160332
Abstract: Continuous rapid-flow electron spin resonance (ESR) was used to detect poly(vinyl alcohol) (PVA)-derived carbon-centered radicals, in order to characterize the short-lived intermediate radicals in the initial stage of the graft polymerization of PVA. ESR spectra… read more here.
Keywords: carbon; rapid flow; carbon centered; spin ... See more keywords
Spin-Trapping Analysis of the Thermal Degradation Reaction of Polyamide 66
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DOI: 10.3390/polym14214748
Abstract: The radical mechanisms of the thermal degradation of polyamide 66 (PA66) occurring under a vacuum at a temperature range between 80 °C and 240 °C (which includes the temperature of practical applications) were investigated using… read more here.
Keywords: thermal degradation; spin trapping; reaction; analysis ... See more keywords
Spin Trapping Analysis of Radical Intermediates on the Thermo-Oxidative Degradation of Polypropylene
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym15010200
Abstract: The purpose of this study is to investigate the thermo-oxidative degradation behavior of polypropylene (PP) by comparing three types of pristine PP granules (consisting of homopolymer, random copolymer, and block copolymer) with their corresponding oxidized… read more here.
Keywords: thermo oxidative; spin trapping; spin; oxidative degradation ... See more keywords