Spin and valence isomerism in cyanide-bridged {FeMII} (M = Fe and Co) clusters.
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DOI: 10.1039/d1dt01298c
Abstract: Two cyanide-bridged V-shaped isostructural trinuclear complexes [{(Tp*)FeIII(CN)3}2MII(bztpen)]·Sol (M = Fe, Sol = CH3OH·3H2O, 1; M = Co, Sol = 2CH3OH·2H2O, 2; bztpen = N-benzyl-N,N',N'-tris(2-methylpyridyl)ethylenediamine; Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) were synthesized and characterized. The bztpen ligand serves… read more here.
Keywords: cyanide bridged; spin valence; valence isomerism; cyanide ... See more keywords
Synergetic Spin-Valence Catalysis Mechanism in Oxygen Reduction Reactions on Fe-N-C Single-Atom Catalysts
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DOI: 10.1039/d3ta00555k
Abstract: The spin and valence states of active sites have a direct and crucial bearing on the activity of transition-metal-based catalysts. However, modulating spin and valence states based on the synergistic... read more here.
Keywords: valence catalysis; spin valence; catalysis mechanism; synergetic spin ... See more keywords