Chiral Cyclohexyl-Fused Spirobiindanes: Practical Synthesis, Ligand Development, and Asymmetric Catalysis.
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DOI: 10.1021/jacs.8b07125
Abstract: 1,1'-Spirobiindane has been one type of privileged skeleton for chiral ligand design, and 1,1'-spirobiindane-based chiral ligands have demonstrated outstanding performance in various asymmetric catalysis. However, the access to enantiopure spirobiindane is quite tedious, which obstructs… read more here.
Keywords: cyclohexyl; cyclohexyl fused; spirobiindane; ligand ... See more keywords