(Electro‐)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex
Sign Up to like & getrecommendations! Published in 2020 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201901278
Abstract: The splitting of N2 into well‐defined terminal nitride complexes is a key reaction for nitrogen fixation at ambient conditions. In continuation of our previous work on rhenium pincer mediated N2 splitting, nitrogen activation and cleavage… read more here.
Keywords: chemical splitting; splitting dinitrogen; electro chemical; rhenium pincer ... See more keywords
Halide Effects in Reductive Splitting of Dinitrogen with Rhenium Pincer Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00973
Abstract: Transition metal halide complexes are used as precursors for reductive N2 activation up to full splitting into nitride complexes. Distinct halide effects on the redox properties and yields are frequently observed yet not well understood.… read more here.
Keywords: reductive splitting; effects reductive; halide effects; splitting dinitrogen ... See more keywords