Water Microdroplets Surrounded by Alcohol Vapor Cause Spontaneous Oxidation of Alcohols to Organic Peroxides.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c04092
Abstract: Using real-time mass spectrometric (MS) monitoring, we demonstrate one-step, catalyst-free spontaneous oxidation of various alcohols (ROH) to key reactive intermediates for the formation of ROO- compounds on the surface of water microdroplets surrounded by alcohol… read more here.
Keywords: water; water microdroplets; organic peroxides; alcohol ... See more keywords
Spontaneous oxidation of I- in water microdroplets and its atmospheric implications.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04288f
Abstract: Atomic and molecular iodine, I˙ and I2, play important roles in the atmosphere, such as the catalytic depletion of ozone and the oxidation of gaseous elemental mercury. It is known that the major source of… read more here.
Keywords: oxidation; oxidation water; water; chemistry ... See more keywords