Two-Step Thermoinduced Metal-to-Metal Electron Transfer and ON/OFF Photoswitching in a Molecular [Fe2Co2] Square Complex.
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DOI: 10.1021/acs.inorgchem.0c02053
Abstract: A cyanide-bridged [Fe2Co2] molecular square complex, {[Fe(Tp)(CN)3]2[Co(L)2]2}(BF4)2·2CH3CN·6H2O [1; Tp = hydrotris(pyrazol-1-yl)borate and L = bis(1-ethyl-1H-imidazol-2-yl)ketone], has been synthesized and characterized fully by single-crystal X-ray diffraction, (photo)magnetic measurements, optical reflectivity, and other physical measurements. 1 exhibits… read more here.
Keywords: state; two step; metal; square complex ... See more keywords