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Published in 2017 at "Advanced materials"
DOI: 10.1002/adma.201601861
Abstract: Phosphorescent organic light-emitting diodes (OLEDs) are leading candidates for next-generation displays and solid-state lighting technologies. Much of the academic and commercial pursuits in phosphorescent OLEDs have been dominated by Ir(III) complexes. Over the past decade…
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Keywords:
phosphorescent;
phosphorescent complexes;
complexes efficient;
square planar ... See more keywords
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Published in 2020 at "ChemPlusChem"
DOI: 10.1002/cplu.202000019
Abstract: An understanding of methods to control the structure of self-assembled architectures is central to the efforts of chemists interested in self-assembly synthesis. Metal ions with square-planar geometry are a favorite of metallosupramolecular chemists, as there…
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Keywords:
metal ions;
square planar;
geometry;
structure ... See more keywords
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Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201800144
Abstract: Halogen bonding in self-complementary 1:2 metal-ligand complexes obtained from copper(II) bromide (CuBr2) and seven 2,5dihalopyridines are analyzed using single crystal X-ray diffraction. All presented discrete complexes form 1-D polymeric chains connected with C–X···Br–Cu halogen bonds…
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Keywords:
bonds square;
copper bromide;
square planar;
halogen ... See more keywords
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Published in 2019 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26031
Abstract: The unified term of trans‐philicity is proposed to cover the trans‐effect/trans‐influence concepts. NMR trans‐philicity ladders are built for a broad series of square planar trans‐Pt(NH3)2(Cl)L and trans‐Pt(CO)2(Cl)L complexes employing 35Cl NMR probe and quantified by…
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Keywords:
trans influence;
philicity;
square planar;
trans philicity ... See more keywords
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Published in 2022 at "ChemistryOpen"
DOI: 10.1002/open.202200061
Abstract: Invited for this month's cover picture are the groups of Masahiro Ikeshita and Takashi Tsuno at Nihon University and Yoshitane Imai at Kindai University (Japan). The cover picture shows the comparison of circularly polarized luminescence…
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Keywords:
platinum complexes;
square planar;
geometry;
enhancement chiroptical ... See more keywords
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Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.11.024
Abstract: Abstract In quest of copper complexes having [CuN3O] cores, [Cu(phen)( l –Val)(H2O)]NO3 (1) and [Cu(bpy)( l –Val)]ClO4 (2) complexes have been synthesized and structurally characterized (phen = 1,10–phenanthroline; bpy = 2,2′–bipyridine). Complex 1 possesses a distorted square-pyramidal, whereas 2…
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Keywords:
square planar;
copper complexes;
activity;
square pyramidal ... See more keywords
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Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.09.084
Abstract: Abstract Five new dithiophosphonic acids ((p-MeO-C6H4)PS(SH)(OR), HLn, (n = 1–5); R = 3-pentyl-, HL1; R = 1-phenyl-1-propyl-, HL2; R = 4-tert-butyl benzyl-, HL3; R = diphenylmethyl-, HL4; R = 4-tert-butylcyclohexyl-, HL5) were prepared by the reaction of Lawesson reagent with the corresponding alcohols. As the acids were…
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Keywords:
pyridine derivatives;
crystallography dft;
square planar;
molecular docking ... See more keywords
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Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114535
Abstract: Abstract Four new Pd(II) complexes with halogenderivatives of 8-quinolinol (HXQ) were prepared: [PdCl(NH(CH3)2)(CQ)] (1), [PdCl(NH(CH3)2)(dClQ)] (2), [PdCl(NH(CH3)2)(dBrQ)] (3) and [PdCl(NH(CH3)2)(BrQ)] (4), where HCQ is 5-chloro-7-iodo-8-quinolinol, HdClQ is 5,7-dichloro-8-quinolinol, HdBrQ is 5,7-dibromo-8-quinolinol and HBrQ is 7-bromo-8-quinolinol.…
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Keywords:
complexes halogenderivatives;
pdcl ch3;
square planar;
cancer ... See more keywords
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Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01908
Abstract: Syntheses of square planar (SP) coordination complexes of gallium(III) are reported herein. Using the pyridine diimine ligand (PDI), we prepared both (PDI2-)GaH (4) and (PDI2-)GaCl (5), which were spectroscopically and structurally characterized. Reduction of PDI…
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Keywords:
proton nmr;
square planar;
planar gallium;
metalloaromaticity ... See more keywords
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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00346
Abstract: Iron carbonyls are known to form 18-electron complexes like Fe(CO)5, Fe2(CO)9, and Fe3(CO)12 having terminal or bridged Fe-CO bonding. Based on genetic algorithm-assisted density functional theory (DFT) calculations, it is predicted that at pressures above…
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Keywords:
iron tetracarbonyl;
square planar;
chemistry;
geometry ... See more keywords
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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02855
Abstract: For a variety of purposes, it is of interest to embed metals in cagelike trans-spanning di(triaryl)phosphine ligands. Toward this end, a combination of P(p-C6H4O(CH2)mCH═CH2)3 [3; m = 4 (a), 5 (b), 6 (c), and 7…
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Keywords:
c6h4o ch2;
triaryl phosphine;
square planar;
trans c6h4o ... See more keywords