Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C1 Chemistry.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08886
Abstract: Methylidene complexes often couple to ethylene complexes, but the mechanistic insight is scant. The path by which two cations [(η5-C5H5)Re(NO)(PPh3)(═CH2)]+ (5+) transform (CH2Cl2/acetonitrile) to [(η5-C5H5)Re(NO)(PPh3)(H2C═CH2)]+ (6+) and [(η5-C5H5)Re(NO)(PPh3)(NCCH3)]+ is studied by density functional theory. Experiments… read more here.
Keywords: h2c ch2; chemistry; sre; ch2 ... See more keywords
Adherence and cumulative bisphosphonate dose in relation to risk of skeletal-related events among older patients with multiple myeloma.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Clinical Oncology"
DOI: 10.1200/jco.2019.37.15_suppl.e18250
Abstract: e18250 Background: Adjuvant intravenous bisphosphonates (IV BP) reduce the risk of skeletal-related events (SRE) in patients with multiple myeloma (MM). We examined the effects of bisphosphonate utilization patterns (adherence, cumulative dose and frequency) on risk… read more here.
Keywords: dose; risk; adherence; skeletal related ... See more keywords