Structural Stability of N-Alkyl-Functionalized Titanium Metal-Organic Frameworks in Aqueous and Humid Environments.
Sign Up to like & getrecommendations! Published in 2017 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.7b15045
Abstract: We demonstrate that the highly photoredox active metal-organic framework (MOF) MIL-125-NHCyp exhibits crystalline and porosity stability in humid environments for more than 30 days as well as increased hydrophobicity compared to the unfunctionalized framework. This… read more here.
Keywords: humid environments; stability alkyl; metal organic; stability ... See more keywords
Stability of alkyl carbocations.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04034d
Abstract: The traditional and widespread rationale behind the stability trend of alkyl-substituted carbocations is incomplete. Through state-of-the-art quantum chemical analyses, we quantitatively established a generally overlooked driving force behind the stability of carbocations, namely, that the… read more here.
Keywords: stability; alkyl carbocations; stability alkyl;