Zn and Ni complexes of pyridine-2,6-dicarboxylates: crystal field stabilization matters!
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DOI: 10.1107/s2056989019007461
Abstract: Different electron configurations for ZnII (d 10) and NiII (d 8) lead to less regular coordination environments for the former: ZnII adopts strongly distorted octahedral or even fivefold coordination spheres whereas NiII favours rather regular… read more here.
Keywords: pyridine dicarboxylates; crystal field; stabilization matters; field stabilization ... See more keywords