Phosphine-Stabilized Germasilenylidene: Source for a Silicon-Atom Transfer.
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DOI: 10.1021/acs.inorgchem.1c01361
Abstract: A phosphine-stabilized germasilenylidene is synthesized following the pathway of SiCl4 oxidative addition at a germylene-phosphine Lewis pair. Low-temperature reduction using {(MesNacnac)Mg}2 resulted in a chlorosilylene intermediate and finally a molecule exhibiting a Ge═Si: motif. Inside… read more here.
Keywords: stabilized germasilenylidene; silicon atom; phosphine stabilized;