Bench‐Stable Cobalt Pre‐Catalysts for Mild Hydrosilative Reduction of Tertiary Amides to Amines and Beyond
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201801605
Abstract: The readily synthesized and bench‐stable cobalt dichloride complex (dpephos)CoCl2 is employed as a pre‐catalyst for a diversity of silane additions to unsaturated organic molecules, including the normally challenging reduction of amides to amines. With regard… read more here.
Keywords: stable cobalt; cobalt; bench stable; hydrosilative reduction ... See more keywords
Synthesis of highly stable cobalt nanorods anchored on a Ti4N3Tx MXene composite for the hydrolysis of sodium borohydride
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Alloys and Compounds"
DOI: 10.1016/j.jallcom.2021.160991
Abstract: Abstract Cobalt-based catalysts are widely used for borohydride hydrolysis, but they are limited by their poor activity and stability. In this study, highly stable cobalt nanorods were facilely anchored on T4N3Tx MXene via hydrothermal synthesis.… read more here.
Keywords: cobalt; hydrolysis; hydrolysis sodium; cobalt nanorods ... See more keywords