A water-stable homochiral luminescent MOF constructed from an achiral acylamide-containing dicarboxylate ligand for enantioselective sensing of penicillamine.
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DOI: 10.1039/c8cc06274a
Abstract: A water-stable homochiral luminescent metal-organic framework (HLMOF), {[Cd(l)(4,4'-bipy)]·DMA·5H2O}n (1), was obtained by a spontaneous symmetry-breaking crystallization from achiral precursors without any enantiopure auxiliary. The homochirality of 1 was confirmed by single-crystal X-ray diffraction and CD… read more here.
Keywords: enantioselective sensing; water; water stable; stable homochiral ... See more keywords