Stable π Radical BDPA: Adsorption on Cu(100) and Survival of Spin
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DOI: 10.1002/cphc.202400852
Abstract: Abstract The adsorption of the radical α,ɣ‐bisdiphenylene‐β‐phenylallyl (BDPA) molecule to the Cu(100) surface was studied using scanning tunnelling microscopy (STM), scanning tunnelling spectroscopy (STS), and density functional theory (DFT) calculations accounting for dispersion forces. BDPA… read more here.
Keywords: radical bdpa; stable radical; bdpa; adsorption ... See more keywords
Stable Radical Cation and Dication of a 1,4-Disilabenzene.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c12908
Abstract: The reaction of (LSi:)2 (1; L = PhC(NtBu)2) with 2 equiv of Me3SiC2C2SiMe3 resulted in the formation of (Me3SiC2)2(Me3Si)2C4Si2(L)2 (2). 2 exhibited a one-electron transfer when treated with 1 equiv of [Ph3C]+[B(C6F5)4]- to yield [(Me3SiC2)2(Me3Si)2C4Si2(L)2]·+[B(C6F5)4]-… read more here.
Keywords: me3si 2c4si2; radical cation; me3sic2 me3si; cation dication ... See more keywords
Viridium: A Stable Radical and Its π-Dimerization.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c13807
Abstract: The discovery of a stable organic radical formed under mild, clean, and efficient light-mediated conditions is reported. The structure of the stable acridinium-based radical photoproduct was unambiguously established by single-crystal X-ray diffraction, mass spectrometry, and… read more here.
Keywords: viridium stable; dimerization; stable radical; radical dimerization ... See more keywords
A Stable Radical in Cationic Dinuclear Rare-Earth Triple-Decker Complexes Featuring Switchable Magnetic Properties.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c11362
Abstract: In quantum information processing, the implementation of qudits─multilevel qubits where d is the number of levels─has been a major challenge that, if resolved, could lead to the acceleration of certain computational tasks. Spin transport measurements… read more here.
Keywords: magnetic properties; rare earth; stable radical; dinuclear rare ... See more keywords
Stable π-radical nanoparticles as versatile photosensitizers for effective hypoxia-overcoming photodynamic therapy
Sign Up to like & getrecommendations! Published in 2021 at "Materials horizons"
DOI: 10.1039/d0mh01312a
Abstract: A stable π-radical is used as a photosensitizer for photodynamic therapy. Under hypoxic conditions, sufficient O2−˙ generation and cytotoxicity were observed addressing the most important hurdle for successful PDT in a tumor microenvironment. read more here.
Keywords: nanoparticles versatile; photodynamic therapy; radical nanoparticles; versatile photosensitizers ... See more keywords