Stable Radical Cation and Dication of a 1,4-Disilabenzene.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c12908
Abstract: The reaction of (LSi:)2 (1; L = PhC(NtBu)2) with 2 equiv of Me3SiC2C2SiMe3 resulted in the formation of (Me3SiC2)2(Me3Si)2C4Si2(L)2 (2). 2 exhibited a one-electron transfer when treated with 1 equiv of [Ph3C]+[B(C6F5)4]- to yield [(Me3SiC2)2(Me3Si)2C4Si2(L)2]·+[B(C6F5)4]-… read more here.
Keywords: me3si 2c4si2; radical cation; me3sic2 me3si; cation dication ... See more keywords
Stable π-radical nanoparticles as versatile photosensitizers for effective hypoxia-overcoming photodynamic therapy
Sign Up to like & getrecommendations! Published in 2021 at "Materials horizons"
DOI: 10.1039/d0mh01312a
Abstract: A stable π-radical is used as a photosensitizer for photodynamic therapy. Under hypoxic conditions, sufficient O2−˙ generation and cytotoxicity were observed addressing the most important hurdle for successful PDT in a tumor microenvironment. read more here.
Keywords: nanoparticles versatile; photodynamic therapy; radical nanoparticles; versatile photosensitizers ... See more keywords