Extracting meaningful standard enthalpies and entropies of activation for surface reactions from kinetic rates
Sign Up to like & getrecommendations! Published in 2020 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-020-01747-2
Abstract: While analyses based on the Arrhenius kinetic model have been successfully applied since its introduction, the Arrhenius model neglects to describe pre-exponential factor in a scientifically meaningful fashion. Since the 1930s, transition-state theory (TST), has… read more here.
Keywords: standard entropy; surface reactions; surface; activation ... See more keywords
Investigation on standard entropy change of metal hydrides and work function of metals
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2020.10.029
Abstract: Abstract We focused on the work function of metals as an index of ion binding property between metals and hydrogen and analyzed the relation between the standard entropy change of metal hydrides and the work… read more here.
Keywords: work function; entropy change; standard entropy; function metals ... See more keywords