Iridium Hydride Mediated Stannane–Fluorine and −Chlorine σ-Bond Activation: Reversible Switching between X-Type Stannyl and Z-Type Stannane Ligands
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DOI: 10.1021/acs.organomet.7b00137
Abstract: Iridium(I) carbonyl hydride Ir(H)(CO)(PPh3)3 (1) cleaves the Sn–F and Sn–Cl bonds of four-coordinate stannanes {o-(Ph2P)C6H4}3Sn(X) (X = F (2a) and Cl(2b)) to afford the stannyl complex [{o-(Ph2P)C6H4}3Sn]Ir(CO) (3) and HX (X = F and Cl)… read more here.
Keywords: switching type; type stannyl; bond; reversible switching ... See more keywords