Designing Reactions with Post-Transition-State Bifurcations: Asynchronous Nitrene Insertions into C–C σ Bonds
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DOI: 10.1016/j.chempr.2018.10.019
Abstract: Summary Discoveries of chemical reactions with potential energy surfaces with post-transition-state bifurcations are increasing in frequency. Although such potential energy surface features are often discovered accidentally, we demonstrate here that they can be designed rationally.… read more here.
Keywords: transition state; post transition; state bifurcations;