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Published in 2017 at "Nature Communications"
DOI: 10.1038/ncomms16115
Abstract: H2 turnover at the [FeFe]-hydrogenase cofactor (H-cluster) is assumed to follow a reversible heterolytic mechanism, first yielding a proton and a hydrido-species which again is double-oxidized to release another proton. Three of the four presumed…
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Keywords:
state;
fefe hydrogenases;
hydride state;
state catalytic ... See more keywords