Controlling the Oxidation State of Copper in Metal-Organic Frameworks for CO Electroreduction to Acetate.
Sign Up to like & getrecommendations! Published in 2025 at "Small"
DOI: 10.1002/smll.202509324
Abstract: The electrochemical carbon monoxide reduction reaction (CORR) represents a promising approach for the conversion of CO into acetate. However, the efficiency and selectivity of CO-to-acetate conversion are hindered by the competing formation of other products.… read more here.
Keywords: copper metal; selectivity acetate; oxidation state; acetate ... See more keywords
Harnessing Bromo/Acyloxy Transposition (BrAcT) and Excited-State Copper Catalysis for Styrene Difunctionalization.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c08984
Abstract: 1,2-Difunctionalization of styrenes, adding two distinct functional groups across the C═C double bond, has emerged as a powerful tool for enhancing molecular complexity. Herein, we report the development of a regioconvergent β-acyloxylation-α-ketonylation of styrenes through… read more here.
Keywords: excited state; bract; state copper; bromo acyloxy ... See more keywords