Articles with "state intramolecular" as a keyword



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Multiple fluorescence of tetraarylimidazole and azomethinocoumarin dyad with dual excited-state intramolecular proton transfer

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Published in 2020 at "Dyes and Pigments"

DOI: 10.1016/j.dyepig.2020.108716

Abstract: Abstract Synthesis and structure of novel dyad which molecule includes two fluorophores - 1,2,4,5-tetraarylimidazole and 8-arylazomethino-7-hydroxycoumarin, are described with the aim to obtain compounds with tunable luminescence. The fluorescent excited states of both fluorofores are… read more here.

Keywords: state; state intramolecular; excited state; fluorescence ... See more keywords

Excited state intramolecular proton transfer involving a four-membered system: Photophysical exploration of an isoindole fused imidazole system

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Published in 2017 at "Journal of Luminescence"

DOI: 10.1016/j.jlumin.2017.02.064

Abstract: Abstract The spectral behaviour of a pharmaceutically important molecule, 1-(2-Hydroxy-5-bromo-phenyl)-3,5-dioxo-1 H -imidazo-[3,4- b ] isoindole (ADBR), has been reported. The photophysical properties of ADBR reveal the occurrence of excited state intramolecular proton transfer (ESIPT) phenomenon… read more here.

Keywords: state; state intramolecular; excited state; system ... See more keywords
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Under different solvents excited-state intramolecular proton transfer mechanism and solvatochromic effect of 2-(2-hydroxyphenyl) benzothiazole molecule

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Published in 2019 at "Journal of Luminescence"

DOI: 10.1016/j.jlumin.2018.10.077

Abstract: Abstract 2-(2-Hydroxyphenyl) benzothiazole molecule was synthesized in experiment (Xu et al., 2017), under solvent environments molecular photophysical phenomena were observed, while this experimental work failed to qualitatively unveil the effect of solvent environments on photophysical… read more here.

Keywords: excited state; different solvents; state intramolecular; proton transfer ... See more keywords
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Speed tunability of the excited-state intramolecular proton transfer process based on seven-membered ring pyrrole-indole H-bond systems

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Published in 2019 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2019.110887

Abstract: Abstract A speed tunable excited-state intramolecular proton transfer (ESIPT) system featuring a seven-membered ring, -NH- type hydrogen bonding pyrrole-indole moiety based on ‘naked’ diazaborepins (NDABs) was exhibited. In this paper, the speed of ESIPT process… read more here.

Keywords: excited state; state; state intramolecular; seven membered ... See more keywords
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Excited state intramolecular proton transfer process in benzazole fluorophores tailored by polymeric matrix: A combined theoretical and experimental study

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Published in 2019 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2019.111710

Abstract: Abstract The effects of the polymeric matrix on the photophysical properties of monomeric dyes reactive to Excited State Intramolecular Proton Transfer (ESIPT) were evaluated by UV–Vis absorption and steady-state and time-resolved emission spectroscopies. A radical… read more here.

Keywords: state; state intramolecular; excited state; polymeric matrix ... See more keywords
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Oxazoline as acceptor moiety for excited-state intramolecular proton transfer

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Published in 2018 at "Tetrahedron"

DOI: 10.1016/j.tet.2018.10.019

Abstract: Abstract Excited state intramolecular proton transfer (ESIPT) is a widespread phenomenon that has been exploited in several analytical and technological applications. Here we describe the synthesis of two ESIPT-active halogen-substituted naphthol-oxazolines that can be conveniently… read more here.

Keywords: state intramolecular; excited state; proton transfer; intramolecular proton ... See more keywords
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Aerobic C(sp2)-H Hydroxylations of 2-Aryloxazolines: Fast Access to Excited-State Intramolecular Proton Transfer (ESIPT)-Based Luminophores.

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Published in 2019 at "Organic letters"

DOI: 10.1021/acs.orglett.9b01350

Abstract: The direct hydroxylation of 2-aryloxazolines via a deprotonative magnesiation using TMPMgCl·LiCl and subsequent oxidation with molecular oxygen or air as a green oxidant is reported. This method proceeds under mild conditions at room temperature with… read more here.

Keywords: state intramolecular; excited state; proton transfer; intramolecular proton ... See more keywords

Precise Manipulation of Excited-State Intramolecular Proton Transfer via Incorporating Charge Transfer toward High-Performance Film-Based Fluorescence Sensing.

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Published in 2023 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c13843

Abstract: Excited-state intramolecular proton transfer (ESIPT) has been widely employed for the design of a variety of functionality-led molecular systems. However, precise manipulation of the excited-state reaction is challenging. Herein, we report a new tactic for… read more here.

Keywords: state; transfer; intramolecular proton; state intramolecular ... See more keywords

The excited-state intramolecular proton transfer properties of three imine-linked two-dimensional porous organic polymers

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Published in 2017 at "Journal of Materials Chemistry C"

DOI: 10.1039/c7tc00123a

Abstract: We report the synthesis and excited-state intramolecular proton transfer (ESIPT) properties of three tris(N-salicylideneaniline)-based (TSA) imine-linked porous organic polymers (POPs) containing C3-symmetric 1,3,5-triarylbenzene (TAB), -tristyrylbenzene (TSB), and -tris(arylethynyl)benzene (TAE) monomer units. The TSA–POPs are fluorescent… read more here.

Keywords: state; state intramolecular; excited state; intramolecular proton ... See more keywords
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A novel 3-hydroxychromone fluorescent probe for hydrogen sulfide based on an excited-state intramolecular proton transfer mechanism

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Published in 2018 at "New Journal of Chemistry"

DOI: 10.1039/c8nj01626g

Abstract: Hydrogen sulfide (H2S) is a signaling gasotransmitter that plays important roles in modulating the functions of different systems. We have designed and synthesized a 3-hydroxychromone-based fluorescent probe A for H2S detection. Probe A is based… read more here.

Keywords: fluorescent probe; excited state; state intramolecular; probe ... See more keywords
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The effect of different environments on excited-state intramolecular proton transfer in 4′-methoxy-3-hydroxyflavone

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Published in 2019 at "Organic Chemistry Frontiers"

DOI: 10.1039/c8qo01111g

Abstract: Excited state intramolecular proton transfer reaction occurs with increasing difficulty in the solvents tested in the order toluene → ACN → DMF. read more here.

Keywords: excited state; proton transfer; state intramolecular; intramolecular proton ... See more keywords