IrIII/NiII-Metallaphotoredox catalysis: the oxidation state modulation mechanism versus the radical mechanism.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc03550d
Abstract: A novel oxidation state modulation mechanism, merging oxidative quenching (IrIII-*IrIII-IrIV-IrIII) and nickel catalytic (NiII-NiI-NiIII-NiI-NiII) cycles, has been illuminated unambiguously for photoredox-mediated iridium(iii)/nickel(ii) dual catalyzed C-O cross-coupling of aryl bromide and alcohol. Quinuclidine participates in a… read more here.
Keywords: modulation mechanism; oxidation state; mechanism; state modulation ... See more keywords
Electrocatalyst design for the conversion of energy molecules: electronic state modulation and mass transport regulation.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03630d
Abstract: Electrocatalytic conversions of energy molecules are involved in many energy conversion processes. Improving the activity of electrocatalysts is critical for increasing the efficiency of these energy conversion processes. However, the tailored design of highly active… read more here.
Keywords: energy; conversion; design; state modulation ... See more keywords
Competitive electronic and steric effects in spin-state modulation of a 3D-Hofmann framework and its extension toward nanoscale
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Materials Chemistry C"
DOI: 10.1039/d3tc00064h
Abstract: Modulating the spin-crossover behaviour in porous coordination polymers is not only an excellent way to address the challenges associated with high-order data storage and processing, but the colour change involved... read more here.
Keywords: steric effects; competitive electronic; spin state; state modulation ... See more keywords