Light-Induced Excited-State Palladium Catalysis for Challenging Couplings
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DOI: 10.1016/j.chempr.2020.05.015
Abstract: Recent work published in Science by Arndtsen and co-workers reports a novel excited-state palladium-catalyzed carbonylation. The key to success was both oxidative addition and reductive elimination steps accelerated by visible light, which allowed challenging aryl… read more here.
Keywords: light induced; state palladium; excited state;
Unactivated Alkyl Chloride Reactivity in Excited-State Palladium Catalysis.
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DOI: 10.1021/acs.orglett.1c02467
Abstract: Excited-state palladium catalysis is an efficient process for the alkylation of diverse organic compounds via the generation of alkyl radicals from alkyl bromides and iodides. However, the generation of alkyl radicals from more stable alkyl… read more here.
Keywords: state palladium; excited state; palladium catalysis;
Excited-State Palladium-Catalyzed Radical Migratory Mizoroki-Heck Reaction Enables C2-Alkenylation of Carbohydrates.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13299
Abstract: Excited-state palladium catalysis has emerged as a promising strategy for developing novel and valuable reactions. Herein, we report the first excited-state Pd-catalyzed 1,2-radical migratory Mizoroki-Heck reaction that enables C2-alkenylation of carbohydrates using readily available 1-bromosugars… read more here.
Keywords: heck; reaction; catalyzed radical; state palladium ... See more keywords