Surface Area Estimation: Replacing the Brunauer–Emmett–Teller Model with the Statistical Thermodynamic Fluctuation Theory
Sign Up to like & getrecommendations! Published in 2022 at "Langmuir"
DOI: 10.1021/acs.langmuir.2c00753
Abstract: Surface area estimation using the Brunauer–Emmett–Teller (BET) analysis has been beset by difficulties. The BET model has been applied routinely to systems that break its basic assumptions. Even though unphysical results arising from force-fitting can… read more here.
Keywords: area estimation; bet; statistical thermodynamic; sorbate ... See more keywords
Adsorption of Congo Red and Methylene Blue onto Nanopore-Structured Ashitaba Waste and Walnut Shell-Based Activated Carbons: Statistical Thermodynamic Investigations, Pore Size and Site Energy Distribution Studies
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano12213831
Abstract: In this paper, an advanced statistical physics adsorption model (double-layer model with two energies) is successfully established. On the basis of this model, statistical thermodynamic functions (e.g., entropy (S), Gibbs free enthalpy (G), and internal… read more here.
Keywords: statistical thermodynamic; energy; based activated; activated carbons ... See more keywords