Surface Area Estimation: Replacing the Brunauer–Emmett–Teller Model with the Statistical Thermodynamic Fluctuation Theory
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DOI: 10.1021/acs.langmuir.2c00753
Abstract: Surface area estimation using the Brunauer–Emmett–Teller (BET) analysis has been beset by difficulties. The BET model has been applied routinely to systems that break its basic assumptions. Even though unphysical results arising from force-fitting can… read more here.
Keywords: area estimation; bet; statistical thermodynamic; sorbate ... See more keywords
Sorption Hysteresis: A Statistical Thermodynamic Fluctuation Theory
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DOI: 10.1021/acs.langmuir.4c00606
Abstract: Hysteresis is observed commonly in sorption isotherms of porous materials. Still, there has so far been no unified approach that can both model hysteresis and assess its underlying energetics. Standard approaches, such as capillary condensation… read more here.
Keywords: hysteresis statistical; sorption hysteresis; thermodynamic fluctuation; statistical thermodynamic ... See more keywords
Statistical Thermodynamic Description of Self-Assembly of Large Inclusions in Biological Membranes
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DOI: 10.3390/cimb46100643
Abstract: Recent studies revealed anomalous underscreening in concentrated electrolytes, and we suggest that the underscreened electrostatic forces between membrane proteins play a significant role in the process of self-assembly. In this work, we assumed that the… read more here.
Keywords: assembly large; self assembly; thermodynamic description; description self ... See more keywords
Adsorption of Congo Red and Methylene Blue onto Nanopore-Structured Ashitaba Waste and Walnut Shell-Based Activated Carbons: Statistical Thermodynamic Investigations, Pore Size and Site Energy Distribution Studies
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DOI: 10.3390/nano12213831
Abstract: In this paper, an advanced statistical physics adsorption model (double-layer model with two energies) is successfully established. On the basis of this model, statistical thermodynamic functions (e.g., entropy (S), Gibbs free enthalpy (G), and internal… read more here.
Keywords: statistical thermodynamic; energy; based activated; activated carbons ... See more keywords