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Published in 2021 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2021.109384
Abstract: Abstract Light is not the only stimuli which can coverts donor-acceptor Stenhouse adducts (DASAs) from the triene to the cyclopentenone form. Here, we firstly demonstrate that Cu2+ can drive linear-to-cyclic isomerization of DASAs in acetonitrile,…
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Keywords:
acceptor stenhouse;
cu2;
donor acceptor;
stenhouse adducts ... See more keywords
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Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-49808-7
Abstract: Donor-acceptor Stenhouse adducts (DASAs) are molecular photoswitches spurring wide interest because of their dynamic photophysical properties, complex photoswitching mechanism, and diverse applications. Despite breakthroughs in modularity for the donor, acceptor, and triene compartments, the backbone…
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Keywords:
stenhouse adducts;
donor acceptor;
acceptor stenhouse;
acceptor ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03761k
Abstract: First generation DASA derivatives can be reversibly isomerized from the coloured, open form to the colourless, closed isomer upon protonation, thus behaving as acidochromic compounds in halogenated organic solvent.
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Keywords:
organic solvent;
stenhouse adducts;
acceptor stenhouse;
acidochromism donor ... See more keywords
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Published in 2024 at "Nanoscale"
DOI: 10.1039/d4nr03942d
Abstract: We present the spontaneous isomerization of donor-acceptor Stenhouse adducts anchored onto a gold surface, visualized using scanning tunneling spectroscopy. Our investigation reveals a palette of molecular arrangements, including those with ferroelectric-like ordering, evolving over time…
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Keywords:
stenhouse adducts;
donor acceptor;
acceptor stenhouse;